Researchers from BITS Pilani and Thermax developed a nickel-based chemical looping method for syngas production that removes the need for an air separation unit. At 850 C and 1 bar, methane conversion reached about 97%, with energy efficiency of 91.2% and 79% lower net energy consumption compared with conventional partial oxidation. Equipment costs fell by 62%, bringing the estimated syngas cost down by 53% to roughly $490 to $530 per ton. The process uses nickel as an oxygen carrier. Air passes over nickel to form nickel oxide, then methane reacts with the oxide to produce syngas while regenerating the nickel. Because methane reacts with lattice oxygen rather than molecular oxygen, the energy-intensive air separation step is no longer needed. The authors note these results are based on equilibrium simulations, so real-world performance will vary. If the approach scales beyond 1 ton per hour, it could lower costs for methanol, dimethyl ether, and other syngas-derived fuels. The paper also includes techno-economic analysis for a 25-year plant life. Anyone tracking low-carbon fuel production or industrial process efficiency should watch whether the oxygen carrier holds up in continuous operation.
