New light-sensitive micro-supercapacitors use hydrogen-treated titanium oxide for record energy storage
researchmatters.inResearchers from IISc, UCL, IIIT Delhi and IIT Bombay developed micro-supercapacitors based on hydrogenated titanium sesquioxide, or H:Ti2O3. Treating Ti2O3 nanoparticles with hydrogen at 400 degrees Celsius added hydroxyl groups and oxygen defects, creating active sites for fast proton exchange. The electrodes reached 82.6 millifarads per square centimeter in a three-electrode test, and the full planar device reached 13.5 millifarads per square centimeter, about seven times better than carbon-based micro-supercapacitors. It kept roughly 88% of its capacitance after 5,000 charge-discharge cycles. Because H:Ti2O3 has an ultra-narrow bandgap, it absorbs infrared light and uses the photothermal effect to boost performance. The device stored 58% more energy under light, with gains up to 98% after eight minutes. The work points toward self-powered microelectronics, smart textiles and implantable sensors using abundant titanium compounds rather than scarce or hard-to-recycle materials.
